There is a bug in Dreamweaver CS3 when creating external style sheets (which—by the way—you should be doing any time your are using style sheets with few exceptions).
Basically, when you enter the style sheet name in the Save As field, it ends up being named as untitled.css, rather than the name you typed. The good news is that Dreamweaver is consistent in that the link to the style sheet that is created uses untitled.css as well.
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